C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type

Full Title

Catalytic reactions performed with catalysts classified in B01J31/00 > Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions > Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement > C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type

Child Classifications

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• B01J 2231/4211 Suzuki-type, i.e. RY + R'B(OR)2, in which R, R' are optionally substituted alkyl, alkenyl, aryl, acyl and Y is the leaving group
• B01J 2231/4233 Kumada-type, i.e. RY + R'MgZ, in which Ris optionally substituted alkyl, alkenyl, aryl, Y is the leaving group and Z is halide
• B01J 2231/4238 Negishi-type, i.e. RY + R'ZnZ, in which R, R' is optionally substituted alkyl, alkenyl, alkynyl, aryl, Y is the leaving group and Z is halide or R'
• B01J 2231/4255 Stille-type, i.e. RY + R'3SnR'', in which R is alkenyl, aryl, R' is alkyl and R'' is alkenyl or aryl
• B01J 2231/4261 Heck-type, i.e. RY + C=C, in which R is aryl
• B01J 2231/4266 Sonogashira-type, i.e. RY + HC-CR' triple bonds, in which R=aryl, alkenyl, alkyl and R'=H, alkyl or aryl
• B01J 2231/4272 via enolates or aza-analogues, added as such or made in-situ, e.g. ArY + R2C=C(OM)Z -> ArR2C-C(O)Z, in which R is H or alkyl, M is Na, K or SiMe3, Y is the leaving group, Z is Ar or OR' and R' is alkyl